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Brc1cnc(nc1)C
Pyrimidine, 5-bromo-2-methyl-
CCCP1(=O)OP(=O)(CCC)OP(=O)(O1)CCC
1,3,5,2,4,6-Trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide
CC1(C)OB(OC1(C)C)B1OC(C(O1)(C)C)(C)C
2,2'-Bi-1,3,2-dioxaborolane, 4,4,4',4',5,5,5',5'-octamethyl-
O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.[Pd].[Pd]
Tris(dibenzylideneacetone)dipalladium
C1CCC(CC1)P(C1CCCCC1)C1CCCCC1.Cc1cc(C)c(c(c1)C)N1CCN(C1=[Ru](=Cc1ccccc1)(Cl)Cl)c1c(C)cc(cc1C)C
Ruthenium,[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)(tricyclohexylphosphine)-, (SP-5-41)-

Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

C[Ru+](Cl)(C)C.Cc1cc(C)cc(c1)P(c1ccc2c(c1c1c(ccc3c1cccc3)P(c1cc(C)cc(c1)C)c1cc(C)cc(c1)C)cccc2)c1cc(C)cc(c1)C.Cc1ccc(cc1)C(C)C.[Cl-] Request for Quotation
Chemical Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl
CAS Number: 944451-24-5
Product Number: AG003C6L(AGN-PC-0W41RH)
Synonyms:
MDL No:
Molecular Formula: C65H71Cl2P2Ru
Molecular Weight: 1086.1828

Identification/Properties

Properties
MP:
>100℃
Storage:
Inert atmosphere;2-8℃;
Form:
Solid
Computed Properties
Molecular Weight:
1041.096g/mol
Hydrogen Bond Donor Count:
0
Hydrogen Bond Acceptor Count:
0
Rotatable Bond Count:
8
Exact Mass:
1040.275g/mol
Monoisotopic Mass:
1040.275g/mol
Topological Polar Surface Area:
0A^2
Heavy Atom Count:
67
Formal Charge:
0
Complexity:
1090
Isotope Atom Count:
0
Defined Atom Stereocenter Count:
0
Undefined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Covalently-Bonded Unit Count:
3
Compound Is Canonicalized:
Yes

Safety Information

GHS Pictogram:
Signal Word:
Warning
UN#:
-
Hazard Statements:
H302-H315-H319-H335
Precautionary Statements:
P261-P305+P351+P338
Class:
-
Packing Group:
-

NMR Spectrum

Other Analytical Data

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Chemical Structure


Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride is a highly specialized catalyst that finds extensive applications in advanced chemical synthesis processes. This complex compound is especially valued for its ability to effectively mediate various asymmetric transformations, enabling the creation of complex molecular structures with high levels of stereocontrol.In chemical synthesis, this ruthenium catalyst is utilized in the catalytic asymmetric hydrogenation of a wide range of substrates, including ketones, imines, and enamides. By leveraging the chiral ligand environment provided by the binaphthyl backbone and the xylyl phosphine groups, this catalyst can promote selective hydrogenation reactions to produce chiral compounds with exceptional enantiomeric purity.Additionally, the incorporation of the p-cymene ligand in the ruthenium center imparts stability and reactivity to the catalyst, allowing for efficient catalytic turnover in various synthetic transformations. The unique combination of structural features in this complex enables chemists to access enantioenriched products that are crucial in the synthesis of pharmaceuticals, agrochemicals, and fine chemicals.Overall, the application of Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride in chemical synthesis represents a cutting-edge approach to achieving stereochemically pure compounds, facilitating the development of new molecules with tailored properties and functionalities.